嘧霉胺气相色谱分析的条件嘧霉胺原药用三氯甲烷或丙酮溶解,在气相色谱仪GC-17A中分析.可是均没有出峰.请问用什么检测器好,还有溶剂和稳定设定.

嘧霉胺气相色谱分析的条件嘧霉胺原药用三氯甲烷或丙酮溶解,在气相色谱仪GC-17A中分析.可是均没有出峰.请问用什么检测器好,还有溶剂和稳定设定.
嘧霉胺气相色谱分析的条件
嘧霉胺原药用三氯甲烷或丙酮溶解,在气相色谱仪GC-17A中分析.可是均没有出峰.请问用什么检测器好,还有溶剂和稳定设定.

嘧霉胺气相色谱分析的条件嘧霉胺原药用三氯甲烷或丙酮溶解,在气相色谱仪GC-17A中分析.可是均没有出峰.请问用什么检测器好,还有溶剂和稳定设定.
气相色谱法同时测定柑桔中抑霉唑、噻菌灵和嘧霉胺残留
赵其阳 焦必宁* 王成秋 付陈梅 郭东梅 杨玉柱
（农业部柑桔及苗木质量监督检验测试中心 重庆 400712）
E-mail:bljiao@tom.com
摘 要 建立了一种快速同时测定柑桔中抑霉唑、噻菌灵和嘧霉胺残留量的气相色谱分析方法.柑桔样品在超
声波振荡条件下经乙酸乙酯—正己烷（体积比为1 :1 ）提取,盐析,浓缩液直接用气相色谱—氢火焰检测器进行测定,
色谱柱为HP- 1701小口径石英毛细管柱（30 m × 0.32 mm × 0.25μm）.农药的添加水平在0.2 5.0 mg/kg 范围时,三
种农药的回收率在84.4%~104.2% 之间,相对标准差为0.39%~8.97%.各农药的检出限在0.012mg/kg~0.19 mg/kg 之间.
该方法快速、灵敏、准确,能满足柑桔农药多残留检测的要求.
关键词 柑桔；气相色谱；农药残留；杀菌剂；嘧霉胺；噻菌灵；抑霉唑
中图分类号 O657.7+1
Simultaneous Determination of Imazalil,Thiabendazole and Pyrimethanil Residues in Citrus
Fruits by Gas Chromatography
Zhao Qiyang,Jiao Bining*,Wang Chengqiu,Fu Chenmei,Guo Dongmei,Yang Yuzhu
(The Citrus Quality Supervision,Inspection and Testing Center of Ministry of Agriculture,Chongqing 400712,China)
Abstract A method for rapid simultaneous determination of imazalil,thiabendazole and pyrimethanil residues in citrus
fruits by using gas chromatography was developed.The sample was extracted with acetic ether/n-hexane(1:1,v/v ) by
ultrasonic.Organic extract was filtered through bed of anhydrous sodium sulfate,follow by concentrated with stream of
nitrogen,and then determined by gas chromatography with electron capture detector.The column used was HP-1701 capillary
column (30 m × 0.32 mm × 0.25 μm).Mean recoveries obtained at fortification levels ranged from 0.2 to 5 mg/kg were 84.104.
2% with relative standard deviations (RSDs) from 0.39 to 8.97%.The limits of quantification (LOQ) were in the range of 0.
012mg/kg~0.19 mg/kg.The method is simple,fast and accurate for the analysis of pesticide multi-residues in citrus fruits.
Key words Citrus fruits; gas chromatography; pesticides residues; bactercide; phyrimethanil; thiabendazole; imazalil
标准上要求用的是DB－1,检测器是FPD.
010-88499131

到这里看看吧！